Interface magnetism in Fe/Alq3 bilayer; interface resolved nuclear resonance scattering studies

نویسندگان

چکیده

Interface magnetism and topological structure of Fe on organic semiconductor film (Alq3) have been studied compared with deposited directly Si (100) substrate. To get information the diffused layer at Fe/Alq3 interface, grazing incident nuclear resonance scattering (GINRS) measurements are made depth selective by introducing a 95% enriched thin 57Fe producing x-ray standing wave within layered structure. Compared growth substrate, where exhibits hyperfine field value 32 T (Bulk Fe), thick Fe- Alq3 interface has found reduced electron density fields providing evidence deep penetration atoms into film. Due to soft nature Alq3, moments relax in plane. At same time, resultant ~43 deg out-of-plane orientation due stressed rough near Si. The evolution Fe-Alq3 is monitored using in-situ magneto-optical Kerr effect (MOKE) during surface small-angle (SAXS) measurements. It that atom tries organize clusters minimize their surface/interface energy. origin 2.4 nm magnetic dead attributed small paramagnetic or superparamagnetic nature. present work provides an understanding interfacial metal-organic interfaces study GI-NRS technique, which probe ferromagnetic layer, otherwise difficult for lab-based techniques.

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ژورنال

عنوان ژورنال: Journal of Magnetism and Magnetic Materials

سال: 2022

ISSN: ['0304-8853', '1873-4766']

DOI: https://doi.org/10.1016/j.jmmm.2022.169663